Wednesday, December 22, 2010

Salt Bridge


SALT BRIDGE
  • Contains a solution of non reacting ions (KCl, KNO3, Na2SO4).
  • It functions is to maintain electrical neutrality while redox reactions proceed at the electrodes.

OXIDATION HALF-CELL (ANODE)
REDUCTION HALF-CELL (CATHODE)
Zn (s) → Zn2+(aq) + 2e-
Cu2+(aq) + 2e- → cu (s)
·         Zn2+ ions enter the solution causing an overall excess of positive charge.
·         Anode loses mass/erode
·         Cl- ions from salt bridge move into anode (Zn) half-cell.
·         Cu2+ ions leave the solution causing an overall excess of negative charge.
·         Cathode gain mass/deposit
·         K+ ions from salt bridge move into cathode (Cu) half-cell.

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